Inorganic Chemistry

Sunday AM

IN3WCC-Room 2

Mechanism and Design in Organometallic Catalysis

Organizer(s) - Peter Budzelaar, Jennifer Love and Deryn Fogg
Chair(s) - Peter Budzelaar

08:00 00024 The Activation of C-H Bonds in Organometallic Ni(I) Complexes Johnson S.A.
08:20 00025 Bis(b-ketiminato) Complexes of Cobalt as Models for Organometallic Radical Polymerization *McNeil W.S., Robson K.C.D.
08:40 00026 Strategies towards Cooperative Bimetallic Catalysts Lightbody O.C., $Stryker J.M.
09:00 00027 Hyperpolarised Studies of Reaction Mechanisms by NMR Spectroscopy Duckett S.B., Lopez-Serrano J., Almeida Lenero K.Q., Dunne J.P., Drent E.
09:40 Coffee Break
10:00 00028 Mechanistic Studies in Enyne Metathesis *Diver S.T.
10:40 00029 NHCs vs. Phosphines: New Insights into Ligand Effects on the Activity of Ruthenium Carbenes in Olefin Metathesis Getty K., *$Kennepohl P.
11:00 00030 The Generation of Efficient Supported Heterogeneous Olefin Metathesis Catalysts Allen D.P., $Grubbs R.H.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Diethard Bohme in WCC-Room 3

IN4WCC-Room 3

Recent Advances on the Chemistry of Porphyrins, Phthalocyanines and Related Macrocycles

Organizer(s) - Pierre Harvey and Roger Guilard
Chair(s) - Pierre Harvey

08:35 Introductory Remarks
08:40 00031 Expanded Porphyrins and Related Systems *$Sessler J.L.
09:20 00032 Heme Coordination Properties in Staphylococcus aureus Isd Proteins from Magnetic Circular Dichroism Spectroscopy *$Stillman M.J.
09:40 Coffee Break
Session Chair - Barry Lever

10:00 00033 Phthalocyanines and Related Systems: Old Dyes, New Materials Torres T.
10:40 00034 The Potency of Corrole Metal Complexes in Catalysis, Medicine, and Photovoltaic Cells Mahammed A., Aviv I., Haber A., *$Gross Z.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Diethard Bohme in WCC-Room 3

IN6Delta-A

Solid-State NMR Spectroscopy in Inorganic Materials (Joint with PT) (joint with PT12)

Organizer(s) - Scott Kroeker and Robert Schurko
Chair(s) - Scott Kroeker

08:00 00035 Nuclear Spintronics via OPNMR in Semiconductors Reimer J.
08:40 00036 Probing the Environment of the Metal Center in Layered Zirconium Phosphates by Zr-91 Solid-State NMR *Huang Y., Yan Z., Zhu J., Kirby C.W.
09:00 00037 New Angles for Measuring the Chemical Shift Anisotropy of Quadrupolar Nuclei *$Grandinetti P.J., Ash J.T., Trease N.M., Dey K.K.
09:40 Coffee Break
10:00 00038 NMR Crystallography Without a Space Group: Structure Solution of a Partially Ordered Layered Silicate Material by Solid-State NMR *$Brouwer D.H., Chmelka B., Eckert J., Levitt M. WITHDRAWN
10:20 00039 Solid State NMR Studies of the Formation of MFI Nanomaterials *Darton R.J., Schneider C., Scheffler F., Fyfe C.A.
10:40 00040 Advances in Homo- and Heteronuclear Correlation Solid-State NMR Spectroscopy: Applications to Nanoscale Catalytic Materials Wiench J.W., Trebosc J., Kumar R., Pruski M.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Diethard Bohme in WCC-Room 3

IN7WCC-Room 5

General

Organizer(s) - Sam Yan
Chair(s) - Sam Yan

08:00 00041 Luminescence Spectroscopy of Square-Planar Platinum(II) Complexes: Pressure-Induced Intra- and Intermolecular Effects *$Reber C., Levasseur-Thériault G., Rodrigue-Witchel A.
08:20 00042 Nonlinear Spatial Temporal Dynamics in the Catalyzed Bromate-Pyrocatechol Reaction Harati M., *Wang J.
08:40 00043 Metal-Organic Frameworks as Materials for Intermediate Temperature Fuel Cell Membranes Hurd J.A., *Thangadurai V., $Shimizu G.K.
09:00 00044 Metal Organic Frameworks as Dual Materials for Fuel Cell Applications *$Shimizu G.K., Hurd J.A., Taylor J.M., Reid J.L., Liang J.
09:20 00045 Thermodynamic Explanations for the Patterns of Reactivity in the Cycloaddition and Reduction Reactions of Cations and Heterocycles Containing Sulphur and Nitrogen Du H., Jenkins H.D.B., Mailman A., $Passmore J., Schriver M.J.
09:40 Coffee Break
10:00 00046 An Ab Initio and Raman Study of Lithium-Sulfate Ion Pairs *Pye C.C., Rudolph W. W.
10:20 00047 Thermolysis and Exposure Experiments of Bis(cyclopentadienyl) Titanium (III) Guanidinate Wasslen Y.A., Tois E., *Haukka S., $Barry S.T.
10:40 00048 Variable Luminescence Energy through the Visible Spectrum for Gold(I) Dithiocarbamate Complexes Baril-Robert F., Reber C.
11:00 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Diethard Bohme in WCC-Room 3


Sunday PM

IN3WCC-Room 2

Mechanism and Design in Organometallic Catalysis

Organizer(s) - Peter Budzelaar, Jennifer Love and Deryn Fogg
Chair(s) - Deryn Fogg

13:40 00119 Organometallic Chemistry by Electrospray Ionization Tandem Mass Spectrometry. Applications in the Mechanism of Olefin Metathesis and the Design of ROMP Catalysts *$Chen P.
14:20 00120 Investigating Organometallic Catalysis in Hydrocarbon Solvents by Electrospray Ionisation Mass Spectrometry Henderson M.A., *$McIndoe J.S.
14:40 00121 New Insights into the Electronic Structure of Ruthenium Carbenes in Olefin Metathesis: Insights from Carbon K-Edge XAS Delgado Jaime M.U., *$Kennepohl P.
15:00 Coffee Break
15:20 00122 Catalytic Metathesis of Alkynes with Nitriles: Synthetic and Mechanistic Advances *$Johnson M.J.A., Geyer A.M., Gary J.B., Wiedner E.S., Kampf J.W.
16:00 00123 Hydroformylation of 1-Alkenes by Newly Synthesized Rhodium N-Heterocyclic Carbene Complexes Kotyk M.W., $Crudden C.M., Praetorius J.M., Webb J.D.
16:20 00124 Rational Design of Diastereoselective Rh-Catalyzed Pauson-Khand Reactions *$Baik M.-H.
17:00 End of Session

IN4WCC-Room 3

Recent Advances on the Chemistry of Porphyrins, Phthalocyanines and Related Macrocycles

Organizer(s) - Pierre Harvey and Roger Guilard
Chair(s) - Silviu Balaban

13:40 00125 Bioinspired Porphyrin and Multiporphyrins: From Enzyme Models to Self-Assembled Multiporphyrins Weiss J.
14:20 00126 Vibrational and DFT Investigation of High-Valent Oxometalloporphyrins Czernuszewicz R.S.
15:00 Coffee Break
Session Chair - Laszlo Kalman

15:20 00127 Solvent Effects on the Electrochemistry and UV-Visible Spectroscopy of Manganese Corroles in Non-Aqueous Media *Kadish K.M., Shen J., Ojaimi M., Gros C.P., Barbe J.-M., Guilard R.
16:00 00128 Shape-Persistant Macrocyclic Complexes as Well-Defined Bimetallic Reaction Sites *$Love J.B., Volpe M., Arnold P.L., Patel D.
16:20 00129 Extending the Self-Organization Algorithm of Chlorosomal Bacteriochlorophylls to Synthetic Pigments *$Balaban T. S.
17:00 End of Session

IN6Delta-A

Solid-State NMR Spectroscopy in Inorganic Materials (Joint with PT) (joint with PT12)

Organizer(s) - Scott Kroeker and Robert Schurko
Chair(s) - Gillian Goward

13:40 Clara Benson Award Lecture presented by Michèle Auger

13:40 00130 Deciphering the Secrets of Novel Antimicrobial Agents and Spider Silk: A Solid-State NMR Investigation *$Auger M.
14:20 00131 Mechanism of Central Dark Line Formation in Biominerals: Solid-State NMR Study of the Transformation of Octacalcium Phosphate to Hydroxyapatite *$Chan J.C.C., Tseng Y.-H., Mou C.-Y.
14:40 00132 Solid-State Chlorine NMR of Organometallic Complexes Rossini A.J., Briscoe G.A., *$Schurko R.W.
15:00 Coffee Break
15:20 00133 Solid State NMR Strategies for the Structural Characterization of Glasses *$Eckert H.
16:00 00134 Solid-State 15N and 13C NMR of Thiazyl Materials *Boeré R.T., Iuga D., Roemmele T.L., Yu X.
16:20 00135 Solid-State NMR of Quadrupolar Nuclei: New Methods for Studying Structure and Dynamics in Minerals and Microporous Materials Wimperis S.
17:00 End of Session

INPWCC-2E-2H

Posters

Organizer(s) - Scott Kroeker
Chair(s) - Scott Kroeker

From 17:00 until 19:00

17:00 00136 Structures, Stabilities, and Properties of Divalent Copper Bound to His-Gly Tetrapeptides *Rauk A., Barry S.D., Rickard G.A., Pushie M.J.
17:00 00137 Synthesis and Electrochemical Properties of Ferrocene-Nucleic Acid Conjugates Song H., *Kraatz H.-B.
17:00 00138 Towards a FRET-Based ATP Biosensor Using Quantum Dot/Aptamer-Based Complexes Revesz E., Lai E.P.C., *$DeRosa M.C.
17:00 00139 A Study on Possible Interactions of Nanoparticles with Biological Molecules Kavianpour A., *$Kraatz H.-B.
17:00 00140 Nano-Structural Assembly of Dendrimers Lataifeh A., *$Kraatz H.-B.
17:00 00141 35/37Cl Solid-State NMR and Computational Investigations of the Chloride Ion Environment in Amino Acid Hydrochloride Salts $Chapman B.P., Bryce D.L.
17:00 00142 Selective Tuning of the Optoelectronic Properties of Dithieno[3,2-b:2',3'-d]phosphole Materials Dienes Y., Baumgartner T.
17:00 00143 Cationic Dithieno[3,2-b:2´,3´-d]phospholes: A New Building Block for Luminescent, Conjugated Polyelectrolytes Durben S., Dienes Y., *$Baumgartner T.
17:00 00144 Investigation of Reactive Species by Matrix Isolation FTIR and Time-of-Flight MS. Thermal Fragmentation of the Guanidinato Aluminum Amide Precursor [Me2NC(NiPr)2]Al(NMe2)2 Ziffle L.C., Kenney A.P., Barry S.T., *$Müller J.
17:00 00145 Coordination and Supramolecular Chemistry of Alkali Metal-Crown Ether Cations and Group 13 Hydride Anions Onut L., *McGrady G.S., Decken A.
17:00 00146 A Quantum Chemical Study of the Ring Opening of Cyclohexene on a Brønsted Acid Site Mackie I.D., DiLabio G.A., $Govindhakannan J., Ring Z.
17:00 00147 The Influence of the Local Environment on the Spectroscopic Properties of Tellurium Elder P.J.W., *Vargas-Baca I.
17:00 00148 Investigations of the Perfluoroaryl Boron Dervatives of BODIPY Dyes Bonnier C., *Piers W.E., Thompson A.
17:00 00149 Boron Analogues of Guanidinate Ligands Corrente A.M., Chivers T.
17:00 00150 Mechanism and Design in Homogeneous Chromium Ethylene Trimerization Catalysis *Jabri A., $Gambarotta S.
17:00 00151 Synthesis of Supported Heteroleptic Complexes for Use in Catalysis Jones R.C., $Canty A.J., *Gardiner M.G.
17:00 00152 Synthesis of Heteroleptic Complexes and their Application in Catalysis Jones R.C., $Canty A.J., *Gardiner M.G.
17:00 00153 Comparative Study of 2,2'-Bipyridine and its Boron-Derivatives: Synthesis and Characterization of Cu(I), Pt(II) and Ru(II) Complexes Sun Y., Ross N., *Wang S.
17:00 00154 Synthesis, Characterization and Chemistry of [RhCl(1,5-Cyclo-octadiene){P(CH2OH)3}] Lorenzini F., Patrick B.O., $James B.R.
17:00 00155 Exploring New Catalyst Designs for Olefin Metathesis Romero P., *Grubbs R.H.
17:00 00156 Theoretical and Experimental Investigation of the Formation of Tetradentate N,S,S,N- Binuclear Transition Metal Complexes from Mononuclear N,S,S,N- Chelates *Bierenstiel M
17:00 00157 Surprising Mechanistic Insights from DFT Modeling of Ruthenium Hydride Catalysts for Alkene Hydrogenation Rowley C.N., Foucault H.M., Fogg D.E., Woo T.K.
17:00 00158 An Investigation into Ruthenium Alkylidyne Complexes Campbell C.D., *$Piers W.E., van der Eide E.F.
17:00 00159 Novel Iron(II) Complexes with Tetradentate P-N-N-P Donor Ligands and their Application in Hydrogenation of Ketones Sui-Seng C., Pütz A.-M., Hadzovic A., Haque F.N., Freutel F., Zimmer-De Iuliis M., Lough A.J., *Morris R.H.
17:00 00160 Investigations of Diastereoselective Control for Bis(salicylaldiminato)copper(II) Cyclopropanation Catalysts Boyd R.C., $Foley S.R.
17:00 00161 Studies toward Cross-Coupling of Aryl Fluorides by Pt(II) Complexes Wang T., *Love J.A.
17:00 00162 Insertion of SnX2 into the Pt-Y (X, Y = Cl, Br) Bond of Dimethylplatinum(IV) Complexes *$Momeni B.Z., Hosseini S.S, Moradi Z.
17:00 00163 The Reaction of Cp*Ir(CO)2 with Pentafluorobenzonitrile: C-F Activation *$Leong W.K., Chan P.K.
17:00 00164 Alkylboronate Tantalum(V) Clusters: A Multifunctional Lewis Acid Cage for Host-Guest Purposes *Fontaine F.-G., Garon C.N., Sigouin O.
17:00 00165 Synthesis, Characterization, and Properties of Conjugated Iron(III) Spin-crossover Complexes *$Lemaire M.T., Dujkic B.
17:00 00166 A Comparative Study of Two p-Benzoquinones: Redox and Coordination Chemistry Trefz T.K., *Hicks R.G.
17:00 00167 In-Situ ATR Investigation of Calcium Phosphate on Magnesium Alloy Substrates Strong M., $Gray-Munro J.
17:00 00168 Transition Metal Complexes Containing Quinone-Type Bridging Ligands Oakley S.R, Hicks R.G
17:00 00169 Chemical Oscillations and Photosensitivity in the Uncatalyzed Bromate-Pyrocatechol System Harati M., *Wang J.
17:00 00170 Catalytic Activity of Au, Pd and Bimetallic Nanoparticles in Ionic Liquids Dash P., *$Scott R.W.J.
17:00 00171 Cobalt-Mediated [5+2] Cycloaddition Reaction: Structure/Reactivity Relationship of g5-Pentadienyl Complexes Ylijoki K.E.O., Witherell R.D., Kirk A.D., McDonald R., Ferguson M.J., *$Stryker J.M.
17:00 00172 Substituted Crown Ethers for Building Metal Organic Rotaxane Frameworks, MORFs Mercer D.J., *$Loeb S.J.
17:00 00173 Pressure-Induced Luminescence Effects on Mo(IV)-Oxo Complexes *$Reber C., Lanthier E.
17:00 00174 In-Situ Near-IR Spectroscopy as a Tool in Catalyst Discovery *Kerton F.M., Soper R.G., Butt S.M.
17:00 00175 Reactivity of Hemilabile Complexes of Transition and Main Group Metals Dureen M.A., Stephan D.W.
17:00 00176 Further Explorations of the Coordination Chemistry of 2-(2'-Anilinyl)-4,4-dimethyl-2-oxazoline *Gossage R.A., Decken A., Quail J.W., Jenkins H.A., Jackson S.M., Eisnor C.R.
17:00 00177 Iron(III) Complexes of Amine-Bis(phenolate) Ligands: Structure, Magnetic Behaviour and Reactivity *Kozak C.M., Roy Chowdhury R., Crane A.K.
17:00 00178 Alkylation of Phosphinimide-Supported Titanium(III) and Titanium(IV) Propargyl Complexes. Titanacyclobutene and 3,3'-Dititanacyclobutene Complexes by Radical and Nucleophilic Addition Morita M., *Stryker J.M.
17:00 00179 H-H Distance in Some Dihydrogen Complexes of Osmium Tardiff B.J., *McGrady G.S., Jagirdar B.
17:00 00180 Molybdenum and Tungsten Sulfide Fluoride Chemistry Gerken M., Hillary W., Nieboer J.
17:00 00181 Crown Ether Ligation and its Effects on the Synthesis, Structure and Reactivity of Low Oxidation State Group 13 Salts Cooper B.F.T., $Macdonald C.L.B.
17:00 00182 Novel Indolylphosphines and their Anion-Binding Affinities Ang M.T.C., Yu J.O., Mulani A., *Browning C.S., $Farrar D.H.
17:00 00183 Self-Assembly of Metal Organic Rotaxane Polygons, MORPs Viljoen E., *$Loeb S.J.
17:00 00184 Investigations into the Generality of Cu(II) Systems as Homogeneous Catalysts for Ethylene Polymerization Olson J.A., *Boyd R.C., $Foley S.R.
17:00 00185 Developing a Viable Interface between Silicon and Neurons: Nanopatterned Surfaces for Understanding the Basics of Neuron Function Daly B., *Giuliani F., $Buriak J.M.
17:00 00186 Electrophilic Phosphinidene Complexes and P-Element Bond Forming Reactions *$Sterenberg B.T., Bolton T.M., Miller L.R., Ulmer T.J.
17:00 00187 Synthesis and Characterization of Palladacyclic Complexes of Imino-Isoindoline and Unsupported c-Diimine Ligands: Effective Pre-Catalysts for Carbon-Carbon Bond Formation Reactions Chitanda J.M., *Quail J.W., $Foley S.R.
17:00 00188 Photochromic Valence Tautomeric Complexes Capable of Tunable Wavelength Photomagnetic Processes Frank N.L., Kopelman R.A., Paquette M.M.
17:00 00189 Synthesis of Geometrically Spin Frustrated Trinuclear Plaquettes: Building Blocks for Molecular Magnetic Materials Hatnean J.A., *Johnson S.A.
17:00 00190 Lanthanide Clusters: Synthesis, Characterisation and Spectroscopic Study of New Materials Baril-Robert F., Reber C., Petit S., Luneau D.
17:00 00191 Voltammetric Modelling of the Relationship between S4N4 and S3N3- *Chivers T., $Boeré R.T., Roemmele T.L.
17:00 00192 Organophosphines Bearing Pendant Acetylenes $Greenberg S., *Stephan D.W.
17:00 00193 Di-N-Heterocyclic Carbenes as Bridging Ligands in Dirhodium Complexes *Wells K.D., McDonald R., Ferguson M.J., $Cowie M.
17:00 00194 Using Coordination Chemistry to Control the Threading and Unthreading in Pseudorotaxane Ligands Sharma S., *$Loeb S.J.
17:00 00195 Organoiron Polymers Containing Rigid and Flexible Linkages *Abd-El-Aziz A.S., Vakili S.A.C., Hegmann T.
17:00 00196 Novel Coordination Compounds Based on Water Soluble Cysteine-Containing Organoiron Complexes *Abd-El-Aziz A.S., Vakili S.A.C., Kroeker S.
17:00 00197 Coordination Polymers of Bis(cyclopentadienyliron)arene Complexes Containing Cysteine Moieties *Abd-El-Aziz A.S., Winram D.J., Vakili S.A.C., Kroeker S.
17:00 00198 Redox-Dependent Isomerization in Cp*RuII/RuIII Complexes containing the Scorpionate Hydrotris(methimazolyl)borate Ligand *$Goh L.Y., Kuan S.L., Leong W.K., Webster R.D.
17:00 00199 Electron Transfer Reactions of the {(Nickel(II)cyclam)}.Cucurbituril[8] Inclusion Complex Hart L.A., *$Haines R.I.
17:00 00200 Investigations of Multiple-Quantum Off-Magic Angle Spinning NMR Aguiar P.M., Michaelis V.K., $Kroeker S.
17:00 00201 Characterization of Simple Paramagnetic Solids by Fast MAS NMR Spectroscopy Sidhu P.S., Aguiar P.M., *Kroeker S.
17:00 00202 6,7Li Solid State NMR Study of Li-Ion Mobility in LiMn2O4: Microscopic Insight into a Promising New Cathode Material Davis L.J.M., Cahill L.S., Chapman B., *Goward G.R.
17:00 00203 NMR Studies of Speciation and Homogeneity in Cesium Borosilicate Glasses McKinley C., Aguiar P.M., *$Kroeker S.
17:00 00204 Solid-State 31P and 13C NMR of Extremely Bulky Phosphines *Boeré R.T., Iuga D., Hazendonk P.
17:00 00205 A Multi-Nuclear Solid-State NMR Study of Layered Metal Phosphates Zhu J., *Huang Y.
17:00 00206 Probing the Local Structure of Ionic Liquid Salts with 35Cl, 79Br and 127I Solid State NMR Gordon P.G., Brouwer D.H., $Ripmeester J.
17:00 00207 A Solid-State NMR Study of Glass Crystallization Behavior Longstaffe J.G., Zwanziger J.W., Schneider J.F.
17:00 00208 S-33 and K-39 Solid State NMR of Potassium Sulfates *Moudrakovski I., Lang S., Patchkovskii S., Ripmeester J.
17:00 00209 NMR study of Fluoride-Doped Alkaline Silicate Glasses Karpukhina N.G., Zwanziger J.W., Werner-Zwanziger U., Kiprianov A.A.
17:00 00210 Magnetic Shielding Tensors of Hydridic Protons in Transition-Metal Hydrides Wang M., *$Wasylishen R.E.
17:00 00211 A 109Ag, 13C and 2H NMR and Quantum Chemical Study of Solid Organosilver Compounds Liu B., *Penner G.H.
17:00 00212 A Solid-State Phosphorus-31 NMR Investigation of a Multiple Spin Rhodium-Triphosphine Complex Bernard G.M., Feindel K.W., *$Wasylishen R.E.
17:00 00213 A Preliminary Arsenic-75 NMR Study of Arsenic Containing Solids *Penner G.H., Liu B.
17:00 00214 A Solid-State 51V NMR Investigation of the Magnetic Shielding and Quadrupolar Coupling of [V(O)(ONMe2)2]2O Teymoori R., Bernard G.M., *$Wasylishen R.E.
17:00 00215 Ultrahigh-Field NMR Studies of Nitrogen Doping and Spin-Lattice Relaxation in Two Polytypes of Silicon Carbide *Bain A.D., $Hartman J.S., Berno B.
17:00 00216 A Multinuclear Solid-State NMR Study of Platinum Mono- and Bisdithiolene Species Tang J.A., Kogut E., Lough A.J., Widdifield C.M., Fekl U., *Schurko R.W.
17:00 00217 Investigation of Silver-Phosphorus Halides Complexes [LnAgX] Using Solid-State 109Ag and 31P NMR Spectroscopy Chen F., *Wasylishen R.E.
17:00 00218 A Study of Proton Dynamics in Solid Acids Using Solid-State NMR Traer J.W., Soo K.J., *$Goward G.R.
17:00 00219 Big Spins and Big Quadrupoles *$Bain A.D.
17:00 00220 The Offset Compensated DIVAM Experiment Montina T.D., $Hazendonk P., Wormald P.
17:00 00221 Structural Characterization of Produced Water Using Solid-State 13C NMR Techniques *Clewett C.F.M., Corcoran B., Alam T.M., Osantowski E., $Pullin M.J.
17:00 00222 Morphological Studies on the Crystalline Domain in Poly(bistrifluoroethoxy) Phosphazene Using Domain Selective 13C{1H, 19F} MAS NMR Spectroscopy Borisof A.S., $Hazendonk P., Hayes P.G., Iuga A., DeDenus C.
17:00 01138 Synthesis and Solid State NMR Analysis of Rubidium Methane Phosphonate *Vijayakumar M., Traer J.W., Britten J.F., $Goward G.R.

19:00 End of Session


Monday AM

IN3WCC-Room 2

Mechanism and Design in Organometallic Catalysis

Organizer(s) - Peter Budzelaar, Jennifer Love and Deryn Fogg
Chair(s) - Jennifer Love

08:20 00336 Oxidative Addition of Carbon-Oxygen Bonds to Palladium: Towards a Mild, Catalytic Approach to Amino Acid Synthesis *$Arndtsen B.A., Lu Y., Black D.A., Beveridge R.
08:40 00337 Palladacycles versus Chelating N-Heterocyclic Carbene Complexes of Nickel: Champion Catalysts for C-C Bond Forming Reactions Chitanda J.M., Paulose T.A., $Foley S.R.
09:00 00338 Alkenyl and Phosphinite Ligand Effects in Palladium Mediated Organic Transformations *$Fairlamb I.J.S.
09:40 Coffee Break
10:00 Strem Chemicals Award in Pure or Applied Inorganic Chemistry presented by Deryn Fogg

Introduction of Deryn Fogg by Tito Scaiano

10:00 00339 Catalyst Design in Olefin Metathesis and Tandem Catalysis *$Fogg D.E.
10:40 00340 Synthesis and Reactivities of Cp*RhMe2(PMe2CH2AlMe2): Influence of a Lewis Acid Tethered to a Rh(III) Metal Center on the Activity *Fontaine F.-G., Boudreau J., Thibault M.-H., Drouin F.
11:00 00341 Structures and Reactivity of Borane-Appended Late Transition Metal Complexes *Emslie D.J.H., Oakley S.R., Parker K.D., Huk N.L.
11:40 End of Session

IN4WCC-Room 3

Recent Advances on the Chemistry of Porphyrins, Phthalocyanines and Related Macrocycles

Organizer(s) - Pierre Harvey and Roger Guilard
Chair(s) - Ronald Steer

08:20 00342 Porphyrinoids with an Embedded Pyridine Moiety *$Latos-Grazynski L., Mysliborski R., Rachlewicz K.
09:00 00343 Analysis of the Circular Dichroism of Systems Containing Multiple Phthalocyanine or Porphyrin Ligands *$Kobayashi N., Muranaka A.
09:40 Coffee Break

REMINDER
10:00 Strem Chemicals Award in Pure or Applied Inorganic Chemistry Lecture presented by Deryn Fogg in WCC-Room 2

Session Chair - Jean Weiss

10:40 00344 Supramolecular Functionalization of Carbon Nanotubes with Conjugated Porphyrin Oligomers and Polymers *$Adronov A., Cheng F.
11:00 00345 Non-Planar Oligopyrrolic Macrocycles from meso-Alkylidenylporphyrins to Porphyrinogen-Like Macrocycles *$Lee C.H.
11:40 End of Session

IN6Delta-A

Solid-State NMR Spectroscopy in Inorganic Materials (Joint with PT) (joint with PT12)

Organizer(s) - Scott Kroeker and Robert Schurko
Chair(s) - Darren Brouwer

08:20 00346 Recent Applications of Solid-State NMR to the Characterisation of Materials *$Smith M.E.
09:00 00347 Characterization of Multiphases in the System MgO-Al2O3-TiO2, by 17O and 27Al MAS NMR, Rietveld Refinement of X-Ray Diffraction (XRD) Data, and Electron Probe Microanalysis (EPMA) *Flemming R.L., Izawa M., Kirby C.
09:20 00348 39K Solid State NMR in Potassium Salts at 21 T *Moudrakovski I., Lang S., Patchkovskii S., Ripmeester J.
09:40 Coffee Break

REMINDER
10:00 Strem Chemicals Award in Pure or Applied Inorganic Chemistry Lecture presented by Deryn Fogg in WCC-Room 2

10:40 00349 Double Quantum Solid-State 19F MAS NMR Spectrscopy of Novel Tantalum Oxyfluoride Nanoclusters *$Alam T.M., Clawson J.S., Bonhomme F., Thoma S.G., Zheng S., Autschbach J.
11:20 00350 Solid-State 19F NMR Spectroscopy of the IO2F2- and IO2F32- Anions *$Gerken M., Hazendonk P., Iuga A., Mack J.P.
11:40 End of Session

IN7WCC-Room 12

General

Organizer(s) - Sam Yan
Chair(s) - Sam Yan

08:00 00351 Synthesis, Structure and Reactivity of Novel Non-Cyclopentadienyl Organothorium(IV) Cations Cruz C.A., *Emslie D.J.H.
08:20 00352 Synthesis and Catalytic Activity of Chelating N-Heterocyclic Carbene Complexes of Group 10 Metals $Foley S.R., Paulose T.A., *Quail J.W.
08:40 00353 Cumulene Activation Promoted by Adjacent Ir/Ru Centres *Samant R.G., Trepanier S.J., Dutton J., McDonald R., Ferguson M.J., $Cowie M.
09:00 00354 Synthesis and Characterization of Several Key Catalytic Intermediates. Investigation of the Metal-Ligand Bifunctional Mechanism of Asymmetric Catalytic Ketone Hydrogenations $Hamilton R.J., *Bergens S.H.
09:20 00355 Synthesis and Characterization of Stable Titanium(IV) Allenyl and Propargyl Complexes Supported by Phosphinimide Ligand System and Further Transformations into Titanacyclobutene Complexes. Morita M., *Stryker J.M.
09:40 Coffee Break

REMINDER
10:00 Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture presented by Deryn Fogg in WCC-Room 2

10:40 00356 C-F Bond Activation Promoted by Adjacent Metal Centres Anderson D.J., Wigginton J.R., McDonald R., *$Cowie M.
11:00 00357 New Dinitrogen Complexes of Zirconium MacLachlan E.A., Hess F.M., $Fryzuk M.D.
11:20 00358 "NacNac"-Ligands in Complexes of Cu, Cr and Zr Schaper F.
11:40 End of Session


Monday PM

IN2WCC-Room 4

Main Group Compounds in Catalysis, Materials Research and Biochemistry

Organizer(s) - Lothar Stahl and Paul Ragogna
Chair(s) - Paul Ragogna

13:00 00476 Silylium Ion-Like Chemistry *$Reed C.A.
13:40 00477 New Directions in Low Oxidation State Main Group Chemistry Macdonald C.L.B.
14:00 00478 Catenated Phosphorus Cations: A New Direction in the Chemistry of Phosphorus *$Burford N., Carpenter Y.-Y.S., Conrad E.D., Dyker C.A., Riegel S.D., Weigand J.J.
14:20 00479 "Frustrated Lewis Pairs": A New Avenue to Reactivity and Main Group Catalysis *$Stephan D.W., Welch G.C., McCahill J., Chase P.A.
14:40 00480 Emerging Structural and Property Trends of the Cycloaddition Products of SNS+ with para-Quinones *Passmore J., $Mailman A., Decken A., Monroe K.
15:00 Coffee Break
15:20 00481 Electronic Structures of Group 13-16 N-Heterocyclic Carbene Analogues *Tuononen H.M.
15:40 00482 New Approaches to Selenium-Element Bond Formation Dutton J.L., Tabeshi R., Ragogna P.J.
16:00 00483 Supporting Main Group Compounds with Chelating Diamidonaphthalene Ligands: Application and Analysis with Low Coordinate Pnictogenium Cations Spinney H.A., DiLabio G.A., Korobkov I., Richeson D.S.
16:20 00484 A Donor-Stabilization Strategy for the Preparation of Group 13/15 Multiple Bonds Rivard E., Merrill W. A., Fettinger J.C., Power P.P.
16:40 00485 Investigations into the Mechanism of Thermal Hydrosilation on Silicon Surfaces Wright V.A., *$Buriak J.M.
17:00 End of Session

IN4WCC-Room 3

Recent Advances on the Chemistry of Porphyrins, Phthalocyanines and Related Macrocycles

Organizer(s) - Pierre Harvey and Roger Guilard
Chair(s) - Martin Stillman

13:00 00486 Great Adaptability of the Heme-Cysteinate Monooxygenases Family to Very Diverse Substrates and Sophisticated Reactions *$Mansuy D., Lafite P.
13:40 00487 Cationic Porphyrazine Electrochemistry *$Lever A.B.P., Chen J., Qi M., Lee S., Hoffman B.M., Ma Y., Kobayashi N., Yokoyama M., Stefan S.L.
14:00 00488 Photophysics of Soret-Excited Metalloporphyrins *$Steer R.P., Kowalska D., Liu X., Tripathy U., Velate S.
14:20 00489 Oxygen Concentration Imaging in a Single Living Cell Using Phosphorescence Lifetime of Pt-Porphyrin Saito T., Asakura N., Kamachi T., Okura I.
15:00 Coffee Break
Session Chair - Roger Guilard

15:20 00490 Modulation of the Singlet-Singlet Through Space Energy Transfer Rates in Cofacial Bisporphyrin and Porphyrin-Corrole Dyads Gros C.P., Aly S.M., El Ojaimi M., Barbe J.-M., Brisach F., Abd-El-Aziz A.S., Guilard R., Harvey P.D.
16:00 00491 Designs Leading to Photosystems with Unique Properties *Kalman L., Williams J.C., Allen J.P.
16:20 00492 Supramolecular Assembly of Metal Salphen Macrocyclic Complexes *MacLachlan M.J., Hui J.K.H.
16:40 00493 Photosynthetic Models Composed of Porphyrins and Nanocarbon Materials Fukuzumi S., Saito K., Ohtani M.
17:20 End of Session

IN6Delta-A

Solid-State NMR Spectroscopy in Inorganic Materials (Joint with PT) (joint with PT12)

Organizer(s) - Scott Kroeker and Robert Schurko
Chair(s) - David Bryce

13:00 00494 New Selective Techniques for 19F MAS NMR Spectroscopy of Highly Reactive Inorganic Fluorides $Hazendonk P., Gerken M., Iuga A., Iuga D.
13:20 00495 Progress of Solid State NMR Methods for the Characterization of Polyatomic Structural Motifs in Inorganic Compounds and Glasses *$Massiot D., Fayon F., Deschamps M., Montouillout V., Pellerin N., Roiland C., Hiet J., Kempgens P., Florian P.
14:00 00496 Silicophosphates and Calcium Phosphates: Dipolar and J Experiments, First Principles Calculations *Bonhomme C., Gervais C., Coelho C., Pourpoint F., Azais T., Bonhomme-Coury L., Babonneau F., Mauri F.
14:20 00497 Advantages of Performing Solid-State NMR Experiments at High Magnetic Field Strengths *$Wasylishen R.E., Bernard G.M, Feindel K.W., Forgeron M.A.M., Ooms K.J., Pawsey S., Terskikh V.V., Wang M.
15:00 Coffee Break
15:20 00498 Quadrupolar Nuclei: New Decoupling Sequences and R2-HETCOR Experiments *$Amoureux J.P., Trebosc J., Delevoye L., Hu B., Gan Z.
15:40 00499 Solid State NMR Determinations of the Complete 3D Structures of the Complexes of Organic Molecules and Mixtures of Organic Molecules in Zeolite Molecular Sieves *$Fyfe C.A., Lee J.S., Darton R.J., Brouwer D.H., Diaz A.
16:20 00500 The Influence of Alkali Cations on Borate Glass Network Structures: Multinuclear Magnetic Resonance Study Michaelis V., Aguiar P.M., *$Kroeker S.
16:40 00501 High Field NMR of Quadrupolar Nuclei in Alkali Halide Solid Solutions *Ratcliffe C.I., Ripmeester J., Terskikh V.V.
17:00 End of Session

IN7Delta-B

General

Organizer(s) - Sam Yan
Chair(s) - Sam Yan

13:00 00502 [3×3] Mixed Metal Squares and Homometallic Rectangles: Structural and Magnetic Studies Dawe L.N., Thompson L.K.
13:20 00503 Bis(alkylimidazolium)-Based Ionic Liquids and Related N-Heterocyclic Carbene Ligands *Prokopchuk E.M.
13:40 00504 Synthesis, Metallation, and Self-Assembly of a 3+3 Schiff Base Macrocycle Frischmann P.D., *$MacLachlan M.J.
14:00 00505 Chemistry with Novel Shape-Persistent Ligands: Porosity, Coordination, and Guest Exchange Chong J.H., *$MacLachlan M.J.
14:20 00506 The Quest for Versatile Building Blocks for the Self-Assembly of Novel Molecule-Based Materials *$Pilkington M., Chahma M., Wang J. WITHDRAWN
14:40 00507 Design of Novel Organoiron Complexes Containing Three Unique Azo Dyes *Abd-El-Aziz A.S., Shipman P.O., Winram D.J., Harvey P.D.
15:00 Coffee Break
15:20 00508 The Preparation and Structure of Two Novel SO3- and PhNSO-Bridged Diketiminate Aluminum Dimers. Rys A.Z., Bélanger-Gariépy F., Shaver A.
15:40 00509 Properties and Coordination Chemistry of an Atropisomeric N,N Chelating Ligand McCormick T.M., $Wang S.
16:00 00510 Oligo-Nuclear Ru(II) Complexes Based on Tridentate Ligands *$Hanan G.S., Cooke M.W., Chartrand D.
16:20 00511 Using Guanidinates as Ligands for Chemical Vapour Deposition and Atomic Layer Deposition of Copper Coyle J.P., $Barry S.T.
16:40 00512 Some Unusual Reactions of Ferrocenylacetylene with Metal Carbonyls *$Mathur P., Chatterjee S., Das A., Singh A.K., Mobin S.M.
17:00 End of Session


Tuesday AM

IN2WCC-Room 4

Main Group Compounds in Catalysis, Materials Research and Biochemistry

Organizer(s) - Lothar Stahl and Paul Ragogna
Chair(s) - Thomas Baumgartner

08:00 00699 New Electronically Interesting Polymers and Materials Featuring Main Group Elements *$Protasiewicz J.
08:40 00700 Living Anionic Polymerization of P=C Bonds: A Route to New Functional Macromolecules Noonan K.J.T., Gates D.P.
09:00 00701 Applications of New Tellurium-Centered Ligands in Single-Source Precursors of Main Group Metal Tellurides *Chivers T., Ritch J.S.
09:20 00702 Amidinates and Guanidinates as Ligands for Thin Film Precursors Brazeau A.L., DiLabio G.A., *$Barry S.T.
09:40 Coffee Break
10:00 00703 NLO Studies of Main-Group Systems Yang Q., Elder P.J.W., *Vargas-Baca I.
10:20 00704 New Trimethylsilylchalcogen Reagents for Nanocluster Assembly *$Corrigan J.F., MacDonald D.G., Khadka C., Ahmar S., Vijayaratnam N.
10:40 00705 Transition Metal Complexes of Neutral Radical Thiazyl Ligands: Intermolecular Contacts in the Solid State and the Resulting Magnetic Properties *$Preuss K.E., Hearns N.G.R., Wu J., Madhu N.T.
11:00 00706 The First [1]Molybdarenophanes. Novel Precursors for Organometallic Polymers? Lund C.L., Schachner J.A., *Müller J., Quail J.W.
11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Joseph Hubert in WCC-Room 3

IN3WCC-Room 2

Mechanism and Design in Organometallic Catalysis

Organizer(s) - Peter Budzelaar, Jennifer Love and Deryn Fogg
Chair(s) - Deryn Fogg

08:00 00707 Intramolecular C-H Activation Directed Self-Assembly of an Organoplatinum(II) Molecular Square: Structural and Mechanistic Study *Zhao S.-B., $Wang S.
08:20 00708 A Remarkably Active, Formally Zwitterionic Ruthenium Precatalyst for the Transfer Hydrogenation of Ketones that Does Not Feature an Ancillary Ligand N-H Functionality Lundgren R.J., Rankin M.A., $Stradiotto M.
08:40 00709 Practical Catalytic Hydrogenation Catalysts and Processes *$Abdur-Rashid K., Guo R., Jia W., Chen X., Lough A.J.
09:00 00710 Chemistry and Catalysis of Rhodium(I)-P(CH2OH)3 Complexes Lorenzini F., Patrick B.O., *$James B.R.
09:40 Coffee Break
10:00 00711 Activation of the Elemental Molecules Dinitrogen and Tetraphosphorus and Subsequent N- or P-Atom Transfer Cummins C.C., Curley J.J., Piro N.A., Figueroa J.S., Mendiratta A., Cossairt B.M.
10:40 00712 Spirocyclic, Bimetallic, Bis(iminophosphorano)methandiide Pd(II) Complexes: Synthesis, Crystal Structure and Solution Behaviour Cavell R.G., Ma G., McDonald R.
11:00 00713 Enantioselective Michael Addition and H2-Hydrogenation Reactions Catalyzed by BINAP/1,2-Diamine-Ruthenium(II) Complexes Sui-Seng C., Lough A.J., *Morris R.H.
11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Joseph Hubert in WCC-Room 3

IN6Delta-A

Solid-State NMR Spectroscopy in Inorganic Materials (Joint with PT) (joint with PT12)

Organizer(s) - Scott Kroeker and Robert Schurko
Chair(s) - Robert Schurko

08:20 00714 Stress Fields and Crystallization in Glass Zwanziger J.W., Karpukhina N.G., Longstaffe J.G., Werner-Zwanziger U., Schneider J.
09:00 00715 Oxide Glass Structure: Insights from High Resolution O-17 NMR *$Stebbins J.F.
09:40 Coffee Break
10:00 00716 Optically Polarized NMR of 69/71Ga in Semi-Insulating GaAs *$Hayes S.E., Mui S., Ramaswamy K.
10:20 00717 Solid State NMR Spectroscopic Characterization of Nafion and Nafion Composites Ye G., Mills C., $Goward G.R.
10:40 00718 New Developments in the 129Xe NMR Spectroscopy of Solids *$Ripmeester J., Anedda R., Ananchenko G.S., Soldatov D., Brouwer D.H., Enright G., Moudrakovski I., Udachin K.A., Ratcliffe C.I.
11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Joseph Hubert in WCC-Room 3


Tuesday PM

IN1WCC-Room 3

Concepts and Models in Bioinorganic Chemistry

Organizer(s) - Heinz-Bernhard Kraatz and Pierre Kennepohl
Chair(s) - Heinz-Bernhard Kraatz

13:40 00860 Understanding Metal-Ion Control of S-Nitrosothiol Stability and Reactivity English A.M., Timerghazin Q.K., Peslherbe G.H.
14:20 00861 Properties of the Copper Complexes of the b-Amyloid Peptide of Alzheimer's Disease: Ab Initio and Molecular Dynamics Studies $Raffa D.F., Rickard G.A., *Rauk A.
14:40 00862 Investigation of Cysteine and Methionine Oxidation Using X-Ray Absorption Spectroscopy Karunakaran A., *$Kennepohl P.
15:00 Coffee Break
15:20 00863 Metal Binding in Metallothioneins *$Stillman M.J.
16:00 00864 Biosynthesis of the [NiFe]-Hydrogenase Enzymes: The Nickel Insertion Step Zamble D.B.
16:40 00865 Structural Studies of the Ni Trafficking Proteins: HypA and Nur Kennedy D.C., $Maroney M.J.
17:00 End of Session

IN2WCC-Room 4

Main Group Compounds in Catalysis, Materials Research and Biochemistry

Organizer(s) - Lothar Stahl and Paul Ragogna
Chair(s) - Jens Müller

13:40 00866 Dithienophospholes - Valuable Building Blocks for Organic Electronics Dienes Y., Durben S., *$Baumgartner T.
14:00 00867 A New Class of Organometallic Probes for Correlated In Vitro and In Vivo Imaging Armstrong A.F., Besanger T.R., *$Valliant J.F.
14:20 00868 Ternary Nitrides for Hydrogen Storage: Li-B-N, Li-Al-N and Li-Ga-N Systems Langmi H.W., *McGrady G.S.
14:40 00869 Metallacyclophanes Bridged by Heavier Group 13 Elements: Electrochemistry of [1.1]Metallacyclophanes and Initial Studies on Ring-Opening Polymerization of Strained [1]Metallacyclophanes Schachner J.A., Lund C.L., Orlowski G.A., Kraatz H.-B., *$Müller J.
15:00 Coffee Break
15:20 Alcan Award Lecture presented by Suning Wang

Introduction of Suning Wang by Robert Morris

15:20 00870 Three-Coordinate Organoboron: Impact of Molecular Geometry on Donor-Acceptor Charge Transfer Emission and Applications *$Wang S., Bai D.R., Liu X.Y., Sun Y., Ross N., Zhao S.B., McCormick T.M., Jia W.L., Cui Y., Martic S.
16:00 00871 Group 15 Boraamidinates: Solution Behavior and Redox Reactions of the 1:2 Complexes, LiM[PhB(NtBu)2]2 (M = As, Sb, Bi) Konu J., Chivers T.
16:20 00872 Highly Fluorescent BN-Analogues of Phenanthrene Jaska C.A., Bosdet M.J.D., Parvez M., *Piers W.E.
16:40 00873 Synthesis, Spin Communication, and Coordination Chemistry of a Robust Tridentate Diradical Ligand Anderson K.J., $Hicks R.G., Gilroy J.B., McDonald R., Ferguson M.J., Patrick B.O.
17:00 End of Session

IN5WCC-Room 9

Solid-State Chemistry for Energy Conversion (Joint with MT) (joint with MT7)

Organizer(s) - John Greedan
Chair(s) - Matthew Rosseinsky and Allan Jacobson

13:40 00874 Oxides with Colossal Dielectric Constants: CaCu3Ti4O12 and Related Phases *Subramanian M.A.
14:20 00875 BiAlO3: A High-TC Ferroelectric, and a Performance-Enhancing Additive to Dielectric LaAlO3 $Zylberberg J., *Ye Z.-G., Belik A.A., Takayama-Muromachi E.
14:40 00876 Synthesis and Characterization of a Re-Entrant Relaxor Solid Solution Lei C., *Ye Z.-G.
15:00 Coffee Break
15:20 00877 New Ambient Pressure Bismuth Transition Metal Oxide Phases Bridges C.A., Hughes H., Allix M.M.B., Kuang X., Claridge J.B., $Rosseinsky M.J.
15:40 00878 Crystal and Magnetic Structures of Perovskite Oxyfluorides, PbFeO2F and PbFe.5Ti.5O2.5F.5, Synthesized at High Pressure *Greedan J.E., Katsumata T., Takase A., Inaguma Y., Barbier J., Cranswick L.M.D., Bieringer M.
16:00 00879 Synthesis and Characterization of Oxynitrides, Oxyfluorides and Nitride Oxyfluorides for Use as Photocatalysts, Pigments and Transparent Conductors *$Woodward P.M., Seibel H.A., Kim Y.I., Dolgos M.R.
16:40 00880 Oxides for Catalytic Water Splitting *$Bieringer M.
17:00 End of Session


Wednesday AM

IN1WCC-Room 3

Concepts and Models in Bioinorganic Chemistry

Organizer(s) - Heinz-Bernhard Kraatz and Pierre Kennepohl
Chair(s) - Robert Morris

08:00 01018 Understanding Chemical Interactions Between Heavy Metals and Bio-Ligands *$Burford N., Groom K., Phillips H.A., Saunders C.D.L.
08:40 01019 The Immunoinorganic Chemisty of Cytotoxins and Adjuvants *$Bohle D.S., Bellemare M.-J., Olivier M.
09:20 01020 Synthesis and Characterization of Mercury-Alanine Complexes Saunders C.D.L., *Burford N., Werner-Zwanziger U., McDonald R.
09:40 Coffee Break
10:00 01021 Ultrahigh-Field Multinuclear Solid-State Magnetic Resonance Investigations of Bioinorganic Model Systems *$Bryce D.L., Adiga S., Aebi D., Chapman R.P., Lee P.K., Sward G.D., Zhang L.
10:40 01022 XAS as a Tool for the Characterization of Sulfur-Centered Free Radical Intermediates Martin-Diaconescu V., *$Kennepohl P.
11:00 01023 Vanadium(III) Thiolate Complexes as Nitrogenase Models: Spectroscopic Investigation by High-Frequency and -Field EPR (HFEPR) *Telser J., Krzystek J., Ozarowski A., Chu W.-C., Wang Z.-C., Tsai Y.-F., $Hsu H.-F.
11:20 01024 Heme Proteins in Ionic Liquids Taylor S.A., $Walsby C.J.
11:40 End of Session

IN2WCC-Room 4

Main Group Compounds in Catalysis, Materials Research and Biochemistry

Organizer(s) - Lothar Stahl and Paul Ragogna
Chair(s) - Lothar Stahl

08:00 01025 Bond Activation across Late Transition Metal Nitrogen Bonds *$Gruetzmacher H.
08:40 01026 Design and Tuning of an "Inorganic" Ligand: 1,2-Diaza-3,5-diborolyl Complexes of Transition Metals Ly H.V., Forster T.D., Parvez M., McDonald R., Eisler D., *$Roesler R.
09:00 01027 Electrochemical Studies of Hydrazidophosphines Used in Aqueous Catalysis *Boeré R.T., Majoral J.-P., Sournia-Saquet A., Zablocka M.
09:20 01028 Frustrated Lewis Pairs in Catalysis: Transition Metal-Free Hydrogenation Chemistry Mediated by H2-Activating Main-Group Complexes $Chase P. A., Welch G.C., *Stephan D.W.
09:40 Coffee Break
10:00 01029 A Highly Reactive Ruthenium-Phosphorus p-Bond: Probing Metal-Mediated P-C Bond Formation Rosenberg L., Derrah E.J., Pantazis D.A., McDonald R.
10:20 01030 Catalysts with Chiral Tridentate Supports in Lactide Polymerization *$Mehrkhodavandi P., Douglas A., Labourdette G., Lagaditis P.
10:40 01031 Carbene Stabilization of a Transient Germylene. Synthesis of a Germanium Phosphine Mimic (R3Ge:), Lewis Base Chemistry and Possible Precursor for Anionic Germanium Polymerization Rupar P.A., Jennings M.C., *$Baines K.M.
11:00 01032 Novel Phosphonium Ionic Liquids with Unusual Functionalities Tindale J.J., Ragogna P.J.
11:20 01033 Mechanistic Investigation of Ligand Exchange in Guanidinate Ligand Systems Brazeau A.L., *DiLabio G.A., $Barry S.T.
11:40 End of Session

IN3WCC-Room 2

Mechanism and Design in Organometallic Catalysis

Organizer(s) - Peter Budzelaar, Jennifer Love and Deryn Fogg
Chair(s) - Peter Budzelaar

08:00 01034 Impact of Na- and K-C p-Interactions on the Structure and Binding of M3(sol)n(BINOLate)3Ln Complexes *$Walsh P.J., Wooten A.J., Carroll P.J.
08:20 01035 The Design of New Ancillary Ligands for the Construction of Mononuclear and Dinuclear Transition Metal Complexes: Synthesis, Structure, and Applications in Catalysis *Turculet L., MacInnis M., MacLean D., Hayes C.
08:40 01036 Net Donor Properties of Common 2e Ligands in Organometallic Complexes *$Gusev D.G.
09:00 01037 Mechanistic Studies of the Asymmetric Hydroboration of Vinyl Arenes: A Remarkable Effect of Ligand, Substrate and Reagent *Crudden C.M., Edwards D.R., Hleba Y.B., Lata C.J.
09:40 Coffee Break
10:00 01038 Carbon-Hydrogen and Carbon-Heteroatom Cleavage Reactions at PNP-Supported Metal Centers *$Ozerov O.V., Gatard S., Fan L., Zhu Y., Foxman B.M., Guo C., Musaev D.
10:40 01039 Group V and VI Metal Complexes Bearing N,N'-Disubstituted 1,8-Diaminonaphthalene Ligands Lavoie N., *Korobkov I., Richeson D.S.
11:00 01040 Organometallic Single Electron Transfer Reactivity: Alkyl Halide Activation and Controlled Radical Polymerization with CpCr(Nacnac) Complexes *Smith K.M., Conway J.L., Tang L., Baisch U., Poli R.
11:20 End of Session

IN5WCC-Room 9

Solid-State Chemistry for Energy Conversion (Joint with MT) (joint with MT7)

Organizer(s) - John Greedan
Chair(s) - John Greedan and Yurij Mozharivskyj

08:00 01041 Advanced Magnetocaloric Materials *Pecharsky V.K.
08:40 01042 Chemistry of the Ln5X4 Magnetocaloric Materials (Ln is a Lanthanide, X is a p-Element) *$Mozharivskyj Y., Pecharsky V.K., Miller G.J.
09:00 01043 Thermoelectric Properties of New Materials Forming the Ir3Ge7 Type *$Kleinke H.
09:40 Coffee Break
10:00 01044 Nanostructured Thermoelectrics for Thermal to Electrical Energy Conversion Kanatzidis M.G., Hogan T., Sootsman J., Chung D.-Y., Poudeu F.P., Wu C.-I., Uher C., Kong H.-J.
10:40 01045 Structure of Cd12.7(1)Sb10, the Cadmium Analogue of the Thermoelectric Material "b-Zn4Sb3" Zelinska O.Ya., Bie H., Mar A.
11:00 01046 Oxides as Potential Thermoelectrics *$Maignan A., Hébert S., Pelloquin D., Caignaert V., Pralong V., Kobayashi W.
11:40 End of Session


Wednesday PM

IN1WCC-Room 3

Concepts and Models in Bioinorganic Chemistry

Organizer(s) - Heinz-Bernhard Kraatz and Pierre Kennepohl
Chair(s) - Pierre Kennepohl

13:00 01103 Models of Iron Metalloprotein Active Sites Morris R.H.
13:40 01104 Investigations of the Spectroscopic Features and Reactivity of Metal Salen Radical Complexes Storr T., Wasinger E.C., $Stack T.D.P., Pratt R.C.
14:00 01105 Organometallic 99mTc-Carborane Complexes for Imaging Serotonin Receptors Louie A.S., *$Valliant J.F.
14:20 01106 Reductive Oxygen Activation at Cu(I) or Oxidative Substrate Activation at Cu(II): Two Ways of Selective Catalytic Oxygenations with Molecular Oxygen *Sundermeyer J., Sun H., Raab V., Harms K., Gaoutchenova E.
14:40 01107 Amino Acid-Derived Chelates for Preparing Molecular Imaging and Therapy Agents Armstrong A.F., Louie A.S., Oakley N.A., Parker S, *$Valliant J.F.
15:00 Coffee Break
15:20 01108 Metal-DNA Interactions: Biological and Nanoscience Applications Yang H., Slim M., Kieltyka R., Lecours L., *$Sleiman H.F.
16:00 01109 Bioorganometallic Approach for the Electrochemical Detection of Proteins Based on Ferrocene-Peptide Conjugates Mahmoud K.A., *$Kraatz H.-B.
16:20 01110 One-Pot Syntheses and Radiolabeling of Biodegradable Coordinating Polymers Saatchi K., Häfeli U.O.
16:40 01111 Controlling The Secondary Structure of Peptides Using Ferrocene as a Molecular Scaffold *Chowdhury S., $Kraatz H.-B.
17:00 End of Session

IN2WCC-Room 4

Main Group Compounds in Catalysis, Materials Research and Biochemistry

Organizer(s) - Lothar Stahl and Paul Ragogna
Chair(s) - Kathryn Preuss

13:00 01112 Methylation of Phosphinophosphonium Species to Access Cyclic Di- and Tri-phosphinophosphonium Salts Riegel S.D., *Burford N., Lumsden M., Decken A.
13:20 01113 Heteropolymetallic Complexes of Tetraimidophosphates Robertson S.D., Chivers T.
13:40 01114 Coordination Complexes of Formazans as Precursors to Metallaverdazyls Gilroy J.B., Otieno P.O., Ferguson M.J., McDonald R., *Hicks R.G.
14:00 01115 Gas Phase Spectroscopic Studies of Benzo-2,1,3-Chalcogenadiazoles *Vargas-Baca I., Cozzolino A.F.
14:20 End of Session

IN5WCC-Room 9

Solid-State Chemistry for Energy Conversion (Joint with MT) (joint with MT7)

Organizer(s) - John Greedan
Chair(s) - Patrick Woodward and Mario Bieringer

13:00 01116 Rapid Oxygen Ion Diffusion and Surface Exchange Kinetics in Oxides with Perovskite Related Structure and Ordered A Cations *Jacobson A.J., $Mims C.A.
13:40 01117 Oxygen Activation Rates on Perovskite Oxide Surfaces *$Mims C.A., Jacobson A.J.
14:20 01118 Chemistry of Oxides in Reducing Atmospheres: Conductivity with Oxide and Hydride Ions Rosseinsky M.J., Bridges C.A., Allix M.M.B., Kuang X., Bowman A., Claridge J.B.
15:00 Coffee Break
15:20 01119 Conductive Spinels for High Temperature Applications Martin B.E.N., *$Petric A.
15:40 01120 Anisotropic Diffraction Line Broadening During Charge/Discharge of a Lithium Battery Cathode Material: Are Stacking Faults Really To Blame? *$Whitfield P.S., Le Page Y., Davidson I.J.
16:00 01121 6,7Li 2D Exchange NMR to Study Lithium Ion Dynamics in Phosphates and Fluorophosphates for Cathode Materials Cahill L.S., Goward G.R., Nazar L.F., Iriyama Y.
16:20 01122 Magnetic Properties of Some Cation-Ordered Rock Salt Oxides Derakhshan S., Greedan J.E.
16:40 01123 Synthesis, Structure and Unexpected Magnetic Properties of La3Re2O10 Cuthbert H.L., Greedan J.E., Vargas-Baca I., Swainson I.P.
17:00 End of Session


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